Product ID:CALCO MID-GRADE UNLEADED GASOLINE
MSDS Date:01/25/1992
FSC:9130
NIIN:00-148-7103
MSDS Number: BPLZZ

CHEVRON ENVIRONMENTAL HEALTH CENTER INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804-0054
US

Emergency Phone: 415-233-3737

Info Phone: 415-233-3737

Cage: 0AHD1

TOMS SIERRA CO INC

508 YUBA CITY, CA 95992 US

Telephone: 800-582-3835

Cage: 42142

GASOLINE/CHEVRON PLUS UNLEADED GASOLINE INCLUDES THE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <2.4%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <2.3%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III)

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <6.3%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/15OSTEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III)

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <3%

OSHA PEL 100PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <9.5%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <5%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <4.9%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:LD50 ORAL (RATS) > 5 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE IRRITATION, VISION IMPAIRMENT,
SKIN IRRITATION, NERVOUS SYSTEM DISTURBANCES, COMA, DEATH,
PULMONARY EDEMA, BRONCHITIS, ASPIRATION HAZARD.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE PAIN/SWELLING/REDNESS, BLURRED VISION, SKIN
CRACKING/DEFATTING/DRYNESS, HEADACHE, DIZZINESS, LOSS OF APPETITE,
WEAKNESS, LOSS OF COORDINATION, LOSS OF CONSCIOUSNESS, CONVULSIONS,
DELIRIUM, HALLUCI NATIONS, LUNG INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE
HOLDING EYELIDS OPEN. IF IRRITATION PERSISTS, SEE PHYSICIAN. SKIN:
WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. IF
SYMPTOMS DEVELO P, SEE PHYSICIAN. INGESTION: GIVE WATEROR MILK TO
DRINK. DO NOT INDUCE VOMITING. CONTACT PHYSICIAN.

Flash Point Method:PMCC
Flash Point:<-45.C, -49.F
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:FIRE FIGHTING FOAM, ALCOHOL RESISTANT TYPE (AR)
AFFF, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:EXTREME FIRE HAZARD! DO NOT ENTER ANY ENCLOSED
OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS
MAY INCLUDE SCBA AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:LIQUID EVAPORATES QUICKLY EVEN AT LOW
TEMPERATURES AND FORMS VAPRS WHICH CAN CATCH FIRE AND BURN WITH
EXPLOSIVE VIOLENCE. VAPORS MAY TRAVEL TO REMOTE IGNITIONS

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE SORBENT
MATERIALS OR PUMPING. REMOVE CONTAMINATED SOIL WHERE FEASIBLE.
RELEASES OF PRODUCT SHOULD BE PREVENTED FROM CONTAMINATING SOIL AND
WATER AND FROM ENTERING D RAINAGE AND SEWER SYSTEMS. REPORT SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT USE OR STORE NEAR FLAME, SPARKS
OR HOT SURFACES. USE ONLY IN WELL VENTILATED AREA. KEEP CONTAINER
CLOSED. DO NOT TRANSFER LIQUID TO UNLABELED.
Other Precautions:DO NOT WELD, HEAT OR DRILL CONTAINER. REPLACE CAP OR
BUNG. EMPTIED CONTAINER STILL CONTAINS HAZARDOUS OR EXPLOSIVE VAPOR
OR LIQUID. USE ONLY AS A MOTOR FUEL. DO NOT USE FOR CLEANING,
PRESSURE APPLIANC E FUEL OR ANY OTHER SUCH USE.

Respiratory Protection:NOT NORMALLY REQUIRED. IF OPERATING CONDITIONS
CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED THE RECOMMENDED
EXPOSURE STANDARDS, USE AN APPROVED RESPIRATOR. REFER TO OSHA
BENZENE STANDARD TO DETERMINE T YPE OF RESPIRATOR.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Protective Gloves:NOT NORMALLY REQUIRED.
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:AVOID FREQUENTLY REPEATED SKIN CONTACT BY
WEARING PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
NOTE TO PHYSICIAN: INGESTION OF THIS PRODUCT OR SUBSEQUENT VOMITING CAN
RESULT IN ASPIRATION OF LIGHT HYDROCARBON LIQUID WHICH CAN CAUSE
PNEUMONITIS.

HCC:F1
Boiling Pt:=25.C, 77.F
Vapor Pres:5-15 PSI
Vapor Density:3-4
Spec Gravity:0.7 - 0.8
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID, HYDROCARBON ODOR
Percent Volatiles by Volume:99+

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC.
Stability Condition to Avoid:SPARKS, STATIC ELECTRICITY, OPEN FLAMES
Hazardous Decomposition Products:CARBON DIOXIDE, WATER VAPOR, CARBON
MONOXIDE

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.